Pyrolysis of hybrid polyurethane inorganic thermal insulation: thermogravimetric analysis and FTIR spectra
نویسندگان
چکیده
Purpose. The purpose of this work is to study the process thermal decomposition (pyrolysis) two samples a hybrid organic-inorganic (OIH) heat-insulating material based on data obtained by thermogravimetric analysis and IR-Fourier spectrometry. goal set predetermined following research tasks: find out basic chemical structure OIH (by functional groups), order processes in materials when heated nitrogen, calculate activation energy, pre-exponential factor, determine pyrolysis mechanism. Methods. methods spectrometry were used work. Samples for spectrometric prepared tests using “freezing” experiment method. Results discussion. paper studies structural features polyurethane inorganic insulation traces physicochemical that occur they are under dynamic conditions nitrogen atmosphere up 750 °C. multi-stage nature shown. first sample threestage process. For second sample, proceeds stages. All stages endothermic. This indicates predominance energy costs breaking bonds between organic parts other conclusions. It has been established at all carried according mechanism nucleation growth nuclei (active centers destruction). Analysis IR spectra showed both Desmodur aliphatic isocyanates. Conclusions. changes heating new group — materials. article continuation team authors systematic behavior modern types polymer insulation.
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ژورنال
عنوان ژورنال: ????????????????????????
سال: 2022
ISSN: ['0869-7493', '2587-6201']
DOI: https://doi.org/10.22227/0869-7493.2022.31.04.5-15